Beloit College>Chemistry>Nanochemistry

Chemistry plays a significant role in the emerging interdisciplinary fields of nanoscience and nanotechnology. The nanoscale refers to materials with dimensions on the scale of nanometers (a thousandth of a thousandth of a thousandth of a meter). Control of the material world at the scale of atoms and molecules can produce materials with fundamentally different properties and behavior and has been touted as the next technological revolution. Some questions we will consider include: What nanotechnology already exists? What makes nanomaterials special? How can they be prepared? What tools can be used to study such materials? Three class periods and one laboratory period per week. (U) Offered in even years.

Prerequisite: Previous chemistry or physics background. No specific course is required but you should have experience doing and recording laboratory work.


Spring 2022 Nanochemistry Pearce

First Half

Jan 24 Class:Nanochemistry Basics
Jan 26 Lab:Electrochromic Prussian Blue Thin Films。See required lab notebookformatand using ourmultimeters。来我ab with table of contents started and written purpose and method sections.
Discussion of Reading:Concepts of Nanochemistry,Introduction(pages 1-10).
Discussion of Reading:Nanotech Promise(2007) by Peterson and Heller fromNanoethics: The Ethical and Social Implications of Nanotechnology
Discussion of Reading:无形的巨人:未来nanotechn启用ology(2013), Section 1.2 inEuropean Commission Nanotechnology Report
Discussion of Video:Water filter(2015) from Liquidity Nanotech (youtube)
Discussion of Video:Filtering Drinking Water with Nanofibers(2016) fromMIT Technology Revieworyoutube
Skim:"Electrochromic energy storage devices,"Materials Today, September 2016, 394-402.
Skim:"Rocking Chair Desalination Battery Based on Prussian Blue Electrodes,"ACS Omega, 2017, 4, 1653-1659.
Jan 28 Literature reports1A
Choose arecentnano article that you understand fromNanolettersorACS NANOorNanoscale Advances。船us primarily on a figure or two in the paper and be familiar with the experimental section. Be sure to check for supplementary information (movies and the experimental section may be located there). By end of Wednesday email to claim a paper by including a link to theabstract。Papers that have been selected will be posted here. On Friday, present the figure(s) in a short oral report and answer questions about the experimental details. Test questions in this course will be drawn from these student selected papers, so for the rest of the class your presentation is a practice test.
1. Tiffany:Moisture-Wicking Passive Radiative Cooling Hierarchical Metafabric
2. Takeshi:Defect Engineering in Solution-Processed Polycrystalline SnSe Leads to High Thermoelectric Performance
3.杰克:Printing Air-Stable High-Tc Molecular Magnet with Tunable Magnetic Interaction
4. Frida:Enhancing the mechanical strength and toughness of epoxy resins with linear POSS nano-modifiers
Jan 31 Class:Consumer Products
Lab notebook duefor Electrochromic Prussian Blue. See required lab notebookformat
Feb 02 Lab:Octadecanethiol Monolayer on SilverEveryone will make their own mirror and films. One or two films will be measured for contact angle and the data shared. Get protractorhere。Indicate on the image where you measured the angle.
Movie:Background information(self assembly)
Discussion of Reading:Concepts of Nanochemistry,Concepts(Chapter 1).
Discussion of Reading:Superhydrophobic and superoleophobic properties in nature,"Materials Today, June 2015, 273-285.
Discussion of Video:Lotus Effect(2011) orAustralian Broadcasting Corporation
Discussion of Video:Nasturtium Leaves(2013).
Discussion of Videos:Superhydrophobic Materials(2019).
Discussion of Video:Non-Stick Nanocoating for Efficient Shipping(2011) orEU Research Media Centeroryoutube
Discussion of Video:Anti-icing Superhydrophobic coating(2009) oryoutube
Discussion of Video:LiquiGlide Nonstick Coatings(2019) orKripa Varanasi, MIToryoutube
Skim:"Icephobicity studies of superhydrophobic coatings on concrete via spray method,"Materials Letters, 2018, 233, 263–266.
Discussion of Video:Nanotechnology in Food(2018) orEuropean Food Safety Authorityoryoutube
Feb 04 Literature reports1B
1. Ani:Bio-inspired Track-Etched Polymeric Nanochannels: Steady-State Biosensors for Detection of Analytes
2. Kyle:Removal of Particulate Matter Emissions from a Vehicle Using a Self-Powered Triboelectric Filter
3.Onix:Gold Nanoparticles Adsorbed on Graphene as Nanozymes for the Efficient Elimination of Dye Pollutants
4. Katrina:Nanofiber-Based Proton Exchange Membranes: Development of Aligned Electrospun Nanofibers for Polymer Electrolyte Fuel Cell Applications
5. Lauryn:Biomimetic Hierarchically Silver Nanowire Interwoven MXene Mesh for Flexible Transparent Electrodes and Invisible Camouflage Electronics
Feb 07 Class:Metal Nanoparticles
Lab notebook duefor Octadecanethiol Monolayer on Silver. See above.
Feb 09 Lab:Synthesis of Gold NanoparticlesandSodium Borohydride Synthesis of Silver NanoparticlesandMicrowave-assisted Synthesis of Silver Nanoparticles。You will be assigned one of these syntheses for your lab, but you should be familliar with all of them prior to lab.
Discussion of Reading:Concepts of Nanochemistry,Gold(Chapter 3).
Skim:Crystal structures of gold nanoparticles(jmol).
Discussion of Video: Naomi Halas,InterviewandVideo, PBS Nova (2005) oryoutube
Discussion of Video:Gold Nanoshells, Synthesis and Demonstration(2009) oryoutube
Discussion of Video:Synthesis of Hollow Gold Nanospheres(2010) oryoutube
Skim:Science Translational Medicine, 27 October 2010 orNIH
Skim:Rice team achieves a cancer milestone,Houston Chronicle, November 2012.
Skim:Solar Vapor Generation Enabled by Nanoparticles,ACS Nano, 7(1), 42-49 (2013).
Skim:Using Gold Nanoparticles to Kill Cancer,Physics Central, APS, April 2016 andmovie
Skim:Exploding nanobubbles can kill cancer cells,Science, AAAS, February 2016.
Discussion of Video:Researchers Look To Gold To Help Combat Prostate Cancer, Mount Sinai Health System (2018) oryoutube
Discussion of Reading:Liposuction Goes Nano, C&E News, June 16, 2014, 32-33.
Skim:Gold Nanoparticle-assisted Selective Photothermolysis of Adipose Tissue,Plast. Reconstr. Surg. Global Open, December 2014, 2(12) e283.
Feb 11 Literature reports1C
1.Kidist:Vibrational Properties in Highly Strained Hexagonal Boron Nitride Bubbles
2.Catherin:Fibronectin-Coated Metal–Phenolic Networks for Cooperative Tumor Chemo-/Chemodynamic/Immune Therapy via Enhanced Ferroptosis Mediated Immunogenic Cell Death
3.Cameron:Ligand-assisted deposition of ultra-small Au nanodots on Fe2O3/reduced graphene oxide for flexible gas sensors
4.Prakhar:A novel Ag nanoparticles purification method and the conductive ink based on the purified Ag nanoparticles for printed electronics
5.Thanh:Atmospheric Pressure Mass Spectrometry of Single Viruses and Nanoparticles by Nanoelectromechanical Systems
Feb 14 Class:Nanowires
Lab notebook duefor Gold and Silver Nanoparticles.
Feb 16 Lab:Synthesis of Nickel Nanowires。See using ourmultimeters。到达目的和方法写在你的notebook. You should be able to complete the synthesis portion of the lab today, and will extract the nanorods and characterize them next week.
Discussion of Reading: “Nanoparticles Probe Biosystems,”Materials Today, Feb 2004, 36-43.
Discussion of Reading: “Directed assembly of nanowires,”Materials Today, May 2009, 34-43.
Discussion of Reading: “Programming Assembly,"Inorg. Chem。39, 2258 (2000).
Discussion of Reading: “Nanowires made from silver are super stretchy,"Nature Materials, 16, p. 439–445 (2017).
Discussion of Video:Chad Mirkin(2009) oryoutube
Discussion of Video:Chad Mirkin: Gold Nanoparticles & The Future of Medical Diagnostics(2012) oryoutube
Discussion of Video:Gold NanoparticlesorNOVA "Making Stuff: Smaller"(2011) oryoutube
Discussion of Video:Non-chemotoxic Induction of Cancer Cell Death Using Magnetic Nanowires(2015) orvimeo
Discussion of Video:Gold particles have a new use finding defects in 3D printing(2018) oryoutube
Feb 18 Literature reports1D
1. Jacob:Nanoparticle Surface Engineering with Heparosan Polysaccharide Reduces Serum Protein Adsorption and Enhances Cellular Uptake
2. Jalen:Real-Time Sensing with Multiplexed Optomechanical Resonators
3.Sasank:Directional quantum dot emission by soft-stamping on silicon Mie resonators
4. Damaris:Nanoprogrammed Cross-Kingdom Communication Between Living Microorganisms
5. Antarikish:Nanoengineered Sprayable Therapy for Treating Myocardial Infarction
Feb 21 Class:Photonics
No lab notebook due
Feb 23 Lab: ContinueNickel Nanowireson the same page as your earlier work for this experiment but include a new date. Every group will extract nanowires from the disc. Some groups will prepare an XRD sample and obtain the free nanowire XRD. Others will perform visible microscopy or prepare a labeled SEM sample. All groups will share some characterization data. Measure lengths in SEM images usingImageJ。Your notebook should indicate where you measured.
Discussion of Reading:Concepts of Nanochemistry,Silica(Chapter 2).
Skim: “Nanostructure Polymers for Photonics,”Materials Today, April 2008, pages 48-56.
Discussion of Reading: “P-Ink and Elast-Ink,”Materials Today, July 2008, pages 44-51.
Discussion of Reading: “Smelling chemicals with a photonic nose,”SPIE(2011).
Discussion of Reading: “Keeping Good Company with the Chameleon,” Materials Views (2015).
Skim: “Electronic Qubit Integrated Into Solid-State Switch,” orIEEE Spectrum, 12 Feb 2016.
Skim: “Plasmonics Make Electrochromic Polymers Fast Enough for Video,” orIEEE Spectrum, 28 April 2016.
Skim: “Brighter Displays Come From the Wings of a Butterfly,” orIEEE Spectrum, 3 June 2016.
Discussion of Reading: “Nanophotonic Crystals Separate Real Luxury Watches From the Fakes,” orIEEE Spectrum, 28 June 2016.
Skim: “Flexible and Colorful Electronic Paper Promises a New Look for E-books,” orIEEE Spectrum, 18 October 2016.
Discussion of Video:NatureTech: The Material World, (2006) BBC Part 4 oryoutube
Discussion of Video:Operating Opalux P-Ink Device with a Battery(2010) oryoutube
Discussion of Video:Biomimicry, (2015) General Electric oryoutube
Discussion of Reading: "How to get that old-fashioned light bulb glow without wasting so much energy,"Science, 2016.
Discussion of Video:A Bright Future with Photonics, Cather Simpson (2018) oryoutube
Discussion of Video:Silicon Photonics, Intel Business (2018) oryoutube
Discussion of Reading: “World's Thinnest Optical Waveguide Is Only Three Atoms Thick,” orIEEE Spectrum, 14 August 2019.
Feb 25 Literature reports2A
1. Tiffany:Real-Time Observation and Analysis of Magnetomechanical Actuation of Magnetic Nanoparticles in Cells
2. Takeshi:A Foldable Lithium Sulfur Battery
3.杰克:Structural Color for Additive Manufacturing: 3D-Printed Photonic Crystals from Block Copolymers
4. Amaya:Bio-inspired hierarchical nanoporous carbon derived from water spinach for high-performance supercapacitor electrode materials
5. Frida:Fire-Resistant and Hierarchically Structured Elastic Ceramic Nanofibrous Aerogels for Efficient Low-Frequency Noise Reduction
Feb 28 Class:Semiconductors, Metal Oxides, and Piezoelectricity
Lab notebook duefor Nickel Nanowires.
Mar 02 TEST in 302
Lab: StartHydrothermal Growth of ZnO Nanorods - Synthesis(10 minutes). Arrive with purpose and method for the synthesis written in your notebook on a new page. Leave the prepared tubes next to the oven for inspection.
Discussion of Reading: “Smart, Clean Surfaces,”Materials Today, Nov 2003, pages 43-48.
Discussion of Reading: "Titanium dioxide: environmental white knight?" Environmental Health Perspectives, Apr 2001, page A174-8.
Discussion of Reading/Audio:Self-Cleaning Glass(2009) fromThe Naked Scientists
Discussion of Video:Self-Cleaning Buildings(2012) orEU Research Media Centeroryoutube
Discussion of Video:Smog-Eating Buildings(2013) orCNNoryoutube
Discussion of Video:Use the Power of Light to Clean Your Air(2014), orPURETioryoutube
Discussion of Video:Reduce Building Maintenance(2015) orCeramiCleanoryoutube
Skim: “ZnO – nanostructures, defects, and devices,”Materials Today, May 2007, pages 40-48 but skip the defect section.
Discussion of Reading: “Progress in nanogenerators for portable electronics,”Materials Today, Dec 2012, pages 532-543.
Discussion of Reading: “Breathable and Flexible Piezoelectric ZnO@PVDF Fibrous Nanogenerator for Wearable Applications,”Polymers, July 2018.
Discussion of Reading: “Titanium Dioxide Nanoparticles in Food and Personal Care Products,”ES&T, 2012, 46(4), 2242–2250.
Discussion of Reading: “Activists take aim at nanomaterials in Dunkin Donuts” (2014).
Discussion of Reading: “Dunkin Donuts to remove titanium dioxide from donuts” (2015).
Skim: "Metal oxide nanowire chemical sensors: innovation and quality of life,"Materials Today, December 2016, 559-567.
Mar 04 Literature reports2B
1. Ani:Magnetic Measurement and Stimulation of Cellular and Intracellular Structures
2. Kyle:Flipped Quick-Response Code Enables Reliable Blood Grouping
3.Onix:Aerosol Filtration Efficiency of Common Fabrics Used in Respiratory Cloth Masks
4. Lauryn:Graphene Oxide Composite Membranes for Water Purification
Mar 07 Class:Field Effect Transistors
Class:Carbon Nanotubes
No lab notebook due
Mar 09 Discussion of Reading:Concepts of Nanochemistry,Carbon(Chapter 7).
Discussion of Reading: “Toxicity of single-walled carbon nanotube: How we were wrong?,”Materials Today, January 2010, pages 6-8.
Discussion of Reading: “Carbon nanomaterials for high performance supercapacitors,”Materials Today, July 2013, pages 272-280.
Discussion of Reading: “Ultracentrifugation of single-walled nanotubes,”Materials Today, Dec 2007, 59-60.
Discussion of Reading: “Carbon nanotube-based neat fibers,”Nano Today, Oct 2008, 24-34.
Discussion of Reading: “CNT-Reinforced Ceramics and Metals,”Materials Today, Nov 2004, 44-49.
Discussion of Reading: “Challenges and opportunities for graphene as transparent conductors in optoelectronics,”Nano Today, Dec 2015, 681-700.
Discussion of Video:Blacker than blackorNASA(2010)oryoutube
Discussion of Video:Carbon NanotubesorNOVA "Making Stuff: Stronger"(2011) oryoutube
Discussion of Video:Spinning Carbon NanotubesorCSIRO(2005) oryoutube
Discussion of Video:Space Elevator(2007) orPBS Novaoryoutube
Discussion of Video:Space Elevator interview with Michio Kaku(2011) orDaily Showoryoutube
Discussion of Video:Spinning nanotube fibersorRice University(2014) oryoutube
Mar 11 Literature reports2C
1. KatrinaReconfigurable Micro- and Nano-Structured Camouflage Surfaces Inspired by Cephalopods
2. CameronConductive Nerve Guidance Conduits Based on Morpho Butterfly Wings for Peripheral Nerve Repair
3.CatherinTransdermal Photothermal-Pharmacotherapy to Remodel Adipose Tissue for Obesity and Metabolic Disorders
4. KidistOcean wave energy generator based on graphene/TiO2 nanoparticle composite films
5. PrakharReusability Comparison of Melt-Blown vs Nanofiber Face Mask Filters for Use in the Coronavirus Pandemic
6. ThanhGold Nanoparticles on 3D-Printed Filters: From Waste to Catalysts

Second Half

MIDTERM BREAK
Mar 21 Class:Polymers and Block Copolymers
Lab notebook duefor ZnO.
Mar 23 Lab:PDMS Soft Lithography。目的和方法今天到期。我们将执行ing the DVD version of this lab.
Discussion of Reading: Concepts of Nanochemistry,PDMS(Chapter 4).
Discussion of Reading: "Replication of Vertical Features Smaller than 2 nm by Soft Lithography," J. Am. Chem. Soc., 2003, 125 (49), p 14986 orezproxy
Discussion of Video: "Direct Self-Assembly of Block Copolymers,“陶氏化学(2013)或youtube
Discussion of Video:Polymer Nanotube Composites, Arkema (2009).
Discussion of Video:Drawing carbon nanotubes on paper, MIT (2012) oryoutube
Discussion of Video:Graphene RevolutionorGRAFOID(2015) oryoutube
Discussion of Video:Victor Badminton Rackets(2014) oryoutube.
Discussion of Video:CNT Touch-screen(2011) oryoutube
Discussion of Video:Touch-screens from graphene(2015) oryoutube
Discussion of Video:The Age of Graphene: Samsung's Revolutionary Battery Technology(Dec 2017) oryoutube
Discussion of Video:Why graphene hasn't taken over the world...yet, Verge (July 2018) oryoutube
Discussion of Reading:IBM Pushes Beyond 7 Nanometers (pdf)orIEEE Spectrum, 8 Oct 2018
Skim: "Learning from nature: constructing high performance graphene-based nanocomposites,"Materials Today, May 2017, 210-219.
Mar 25 Literature reports2D
1. JacobVisualization of the Final Stage of Sintering in Nanoceramics with Atomic Resolution
2. DamarisNanoparticles Accumulate in the Female Reproductive System during Ovulation Affecting Cancer Treatment and Fertility
3.Antarikish双亲和力红细胞表面和靶细胞(DART) Enhances Both Organ- and Cell Type-Targeting of Intravascular Nanocarriers
4. AmayaBiodegradable and Flexible Nanoporous Films for Design and Fabrication of Active Food Packaging Systems
5. CatherinTransdermal Photothermal-Pharmacotherapy to Remodel Adipose Tissue for Obesity and Metabolic Disorders
Mar 28 Class:Photovoltaics
Class:Lithium Batteries
Lab notebook duefor PDMS Lab.
Mar 30 Lab:Synthesis of Cadmium Sulfide Nanoparticles。目的和方法今天到期。Lab report due Monday.
Discussion of Reading: “Power from the sun,”spie oemagazine, April 2003, pages 24-27.
Discussion of Reading: “Plastic Photovoltaic Devices,”Materials Today, Sept 2004, pages 36-40.
Discussion of Reading: “Inorganic Photovoltaic Cells,”Materials Today, November 2007, pages 20-27.
Discussion of Reading: “Third Generation Photovoltaic Cells,”Materials Today, November 2007, pages 42-50.
Discussion of Reading: “Nanoelectrodes: energy conversion and storage,”Materials Today, June 2009, pages 20-27. (FIRST 4 PAGES.)
Discussion of Reading: “Organic photovoltaics,”Materials Today, Dec 2012, pages 554-562.
Discussion of Reading: “Recent advances in dye-sensitized solar cells,”Materials Today, Apr 2015, pages 155-162.
Discussion of Video:Solar Nanopaint, Nova (2007) oryoutube
Discussion of Video:CuInGaSSe(2007), History Channel oryoutube
Discussion of Reading: “Who Pays for Grid Expansions When Homeowners Generate Their Own Electricity?,” orIEEE Spectrum, 23 Jan 2014.
Discussion of Reading: “Perovskite Solar Cell Bests Bugbears, Reaches Record Efficiency,” orIEEE Spectrum, 7 Jan 2015.
Discussion of Reading: “Millions of Chinese-Made Solar Panels,”Pacific Standard, 30 Jun 2015.
Discussion of Reading: “Ultrathin Solar Cells for Lightweight and Flexible Applications,” orIEEE Spectrum, 26 Aug 2015.
Discussion of Reading: “Graphene and Perovskite Lead to Inexpensive and Highly Efficient Solar Cells,” orIEEE Spectrum, 8 Sept 2015.
Discussion of Reading: “Will Nanophotonics Save Solar Power Tech?,” orIEEE Spectrum, 14 Apr 2016.
Discussion of Reading: “Perovskite Solar Cells Grow Better With a Dash of Acrylic Glass,” orIEEE Spectrum, 19 Sept 2016.
Discussion of Reading: “Perovskites Become More Stable,” orIEEE Spectrum, 29 Sept 2016.
Discussion of Reading: “Tesla to launch solar roofs,”C&E News, 7 Nov 2016.
Discussion of Reading: “Tesla Teams With Tiny Hawaiian Utility to Store Solar,” orIEEE Spectrum, 16 Mar 2017.
Discussion of Reading: “Rural Rwanda is home to a pioneering new solar power idea,英国广播公司(2017)
Discussion of Reading: “Power From Commercial Perovskite Solar Cells Is Coming Soon,” orIEEE Spectrum, 4 Jan 2019.
Discussion of Video:Ta'u Microgrid, Solar City (2016) oryoutube
Discussion of Video:Tesla Solar Roof, Bloomberg (2017) oryoutube
Discussion of Video:Why Tesla is building city-sized batteries, Verge, August, 2018
Skim: "Use of organic materials in dye-sensitized solar cells,"Materials Today, June 2017, 267-283.
Apr 01 Literature reports3A
1. Tiffany:Underwater Multispectral Computational Imaging Based on a Broadband Water-Resistant Sb2Se3 Heterojunction Photodetector
2. Takeshi:Carbon Nanoscrolls for Aluminum Battery
3.杰克:Ultrahigh-Strength Porous Ceramic Composites via a Simple Directional Solidification Process
4. Frida:Surgical Tumor-Derived Photothermal Nanovaccine for Personalized Cancer Therapy and Prevention
Apr 04 Class:Quantum Dots
Lab notebook duefor CdS synthesis.
Apr 06 Lab: Characterization and Ligand Exchange of Cadmium Sulfide Nanoparticles. Purpose and method due today.
Discussion of Reading:Concepts of Nanochemistry,CdSe(Chapter 5).
Discussion of Video:Synthesis of Cadmium Selenide Quantum Dots, 2011
Discussion of Reading: “Quantum dot field effect transistors,”Materials Today, Sept 2013, pages 312-325.
Skim: "Surface ligands engineering of semiconductor quantum dots for chemosensory and biological applications,"Materials Today, September 2017, 360-376,
Skim: "Water-Soluble NaYF4:Yb,Er(Tm)/NaYF4/Polymer Core/Shell/Shell Nanoparticles with Significant Enhancement of Upconversion Fluorescence,"Chem. Mater., 2007, 341-343 orezproxy
Discussion of Video:Near-Infrared Vision, 2019 oryoutube
Discussion of Video:Practical uses of 100% Quantum Yield Quantum dots, 2017.
Apr 08 Literature reports3B
1. Ani:Shape and Size Control of Artificial Cells for Bottom-Up Biology
2. Kyle:Triboelectric Nanogenerator for Ocean Wave Graded Energy Harvesting and Condition Monitoring
3.Onix:Super-Hydrophilic Leaflike Sn4P3 on the Porous Seamless Graphene–Carbon Nanotube Heterostructure as an Efficient Electrocatalyst for Solar-Driven Overall Water Splitting
4. Lauryn:Colloidal CdS Quantum Dot Fibers Prepared by Electrospinning of Their Wet Gel for Quantum Nanowires
5. Katrina:Restoring Tactile Sensation Using a Triboelectric Nanogenerator
6. Jalen:High Quantum Yield Nitrogen-Doped Carbon Quantum Dot-Based Fluorescent Probes for Selective Sensing of 2,4,6-Trinitrotoluene
Apr 11 Class:Electrons and Magnetism
Lab notebook duefor CdS ligand exchange.
Apr 13 Lab:Synthesis and Characterization of lead perovskite films。目的和方法今天到期。
Discussion of Reading:Crystal structure discovered almost 200 years ago could hold key to solar cell revolutionOregon State Newsroom, July 02, 2020.
Skim:Will the Internet of Things Be Perovskite Powered? Energy Yield Measurement and Real-World Performance of Perovskite Solar Cells in Ambient Light ConditionsIoT 2022, 3, 109–121. January 18, 2021.
Discussion of Reading:Supercrystals: a step towards next-gen ultrabright light sourcesIBM press release: 26 May 2021.
Discussion of Reading:Speeding COVID-19 Drug Discovery with Quantum DotsNIH Director's blog, November 5th, 2020.
Discussion of Reading:Quantum dots as a promising agent to combat COVID-19Appl. Organomet. Chem. June 26 2020.
Apr 15 Literature reports3C
1. Cameron:Macrophages Actively Transport Nanoparticles in Tumors After Extravasation
2. Kidist:Hierarchically Structured Conductive Polymer Binders with Silver Nanowires for High-Performance Silicon Anodes in Lithium-Ion Batteries
3.Prakhar:Tunable Antibacterial Activity of a Polypropylene Fabric Coated with Bristling Ti3C2Tx MXene Flakes Coupling the Nanoblade Effect with ROS Generation
4. Thanh:Carbon Nanotubes as Optical Sensors in Biomedicine
Apr 18 Class: Scanning Probe Microscopies
Lab notebook duefor Lead Halide Perovskites.
Apr 20 Lab:Synthesis of an aqueous ferrofluid。目的和方法今天到期。
Discussion of Reading:Concepts of Nanochemistry,Iron Oxide(Chapter 6).
Discussion of Video:Arsenic Removal, 2006
Skim: "Robust Magnetic/Polymer Hybrid Nanoparticles Designed for Crude Oil Entrapment and Recovery in Aqueous Environments,"ACS Nano, 7(9), 7552-7561 (2013) orezproxy
Discussion of Video:Amazing ferrofluid experiment(first4magnets, 2013)
Discussion of Video:Google Life Sciences Nanoparticle Platform(2014)
Discussion of Video:Monster magnet meets magnetic fluid(Braniac, 2017)
Discussion of Video:How this 50-year-old NASA material could kill cancer(Verge, 2018)
Discussion of Reading:An 18-year-old has found a way to use 'magnetic liquid' invented by NASA to remove harmful microplastics from water(Google Science Fair, 2019)
Discussion of Video:Extraction of microplastics from water using ferrofluids(2018)
Discussion of Audio:Cheap Memory, NPR, January 22, 2012.
Discussion of Video:Amazon Cloud Cam(2018)
Discussion of Video:3D XPoint Announcement(2015) orIntel
Discussion of Video:3D XPoint Memory Technology(2015) orIntel
Discussion of Video:Micron 3D XPoint SSD(2019) orTECHSPOT
Discussion of Reading:Why the Future of Data Storage is (Still) Magnetic Tape (pdf)orIEEE Spectrum, 28 Aug 2018
Apr 22 Literature reports3D
1. Jacob:Evaporation of Water Nanodroplets on Heated Surfaces: Does Nano Matter?
2. Jalen:The Magnetic Genome of Two-Dimensional van der Waals Materials
3.Damaris:Cell Membrane-Camouflaged Nanocarriers with Biomimetic Deformability of Erythrocytes for Ultralong Circulation and Enhanced Cancer Therapy
4. Antarikish:
5. Amaya:Fingerprints of Critical Phenomena in a Quantum Paraelectric Ensemble of Nanoconfined Water Molecules
Apr 25 Class:LEDsandOLEDs
Lab notebook duefor ferrofluid.
Apr 27 SPRING DAY NO CLASS
Apr 29 TEST
May 02 Class:Societal Implications
May 04 Discussion of Reading:Concepts of Nanochemistry, Case Histories (Chapter 8).
Discussion of Reading: "Top ten advances in materials science in the last 50 years", Jonathan Wood,Materials Today, 11(1), 2008.
Discussion of Reading: "The chips are down for Moore's law",Nature, 530, 144–147 (11 February 2016) oraudio
Discussion of Reading: "IBMs Path to 5-Nanometer Transistors",IEEE Spectrum, (5 June 2017).
Discussion of Reading: "Here's Why Nobody's Talking About Nanotech Anymore" (pdf) orTime, Oct 2015.
Discussion of Reading: "A tale of opportunities, uncertainties, and risks",NanoToday, February 2008, pages 56-59.
Discussion of Reading: "Everyday Uses of Nanotechnology" orC&E News, October 10, 2016.
Discussion of Reading: "Are There Nanoplastics in Your Personal Care Products?",Environ. Sci. Technol. Lett., 2017, 4 (7), pp 280–285 orezproxy
Discussion of Video: "Are Engineered Nanoparticles Dangerous?", 2016, Andrew Maynard, Risk Innovation Lab, Arizona State University oryoutube.
Discussion of Reading: "Are quantum dot TVs and their toxic ingredients actually better for the environment?", 2015, Andrew Maynard,The Conversation
Lab: Cleanup (empty counters and drawers and make sure everything is labeled).

Texts

Ludovico Cademartiri and Geoffrey Ozin,Concepts of Nanochemistry, Wiley-VCH (2009), ISBN 978-3-527-32597-9
Nano History, International Institute for Nanotechnology, Northwestern University

Literature Sources

Choose arecent(published since the course started) nano article that you understand fromNanolettersorACS NANOorACS Applied Nano MaterialsorNanoscale Advances(或从另一个期刊的事先批准。)船us primarily on a figure or two in the paper and be familiar with the experimental section. Be sure to check for supplementary information (movies and the experimental section may be located there). By end of Wednesday email to claim a paper by including a link to the paper. Papers that have been selected will be posted in this syllabus. In class, present the figure(s) in a short oral report and answer questions about the experimental details. Test questions in this course will be drawn from these student selected papers, so for the rest of the class your presentation is a practice test.

Primary journals for this course Other available sources Places to find references to articles
American Chemical Society
Nanoletters
ACS NANO
ACS Applied Nano Materials

RSC and NCNST
Nanoscale Advances

Nano Research(Springer)
Journal of Nanoparticle Research(Springer)
Nanoscale Research Letters(Springer)
Some articles in
Nature Nanotechnology
Nanoscale(Royal Society of Chemistry)
Applied Materials and Interfaces(ACS)
Materials Today(Elsevier)
Be sure to use the original reference in these news reports but the summaries might be useful and they are a good way to find interesting articles
Materials News(Materials Research Society)
Nanotechnology news stories(PhysOrg)
Latest nanotechnology articles(AZoNano)

Basis of evaluation

• Class participation in discussion of text readings. Come with questions about anything you do not understand.
• Selection of literature article, identification of main figure, familiarity with the experimental section and a short presentation on the article to the class (every 4 weeks). Your article grade will also be based on whether you understand the selected material and its connection with this course so select something you understand. If you choose wisely, your selection may be on the next test (see below).
• Laboratory experiments require you toplan aheadandrecord your work as you do it。In this course experiments also function as weekly problem sets since they involve measurement, calculation, and discussion. What you record in your bound laboratory notebook will constitute about half the points for this course so follow the requirednotebook format。Notebooks will be due most weeks. Adequately preparing and planning for lab and answering the questions will require several hours outside of class for each experiment.
• Two tests. Interpret the figures and text from literature reports by expanding on what is being illustrated, explaining procedures or techniques, and indicating why it might be important or why the authors included the figure or making connections to our class readings and laboratory work. Tell more than rewriting the caption. Try to use your interpretation to demonstrate additional knowledge beyond what is shown. You should write on each page for about ten minutes. Being able to list the experiments you have done and knowing the techniques and chemicals used in those experiments will be helpful in making connections. Looking atprevious first testsandprevious second testsprovides examples but different papers will have been presented and different content may have been covered and different labs may have been done.

Accommodations

If you have a disability and need accommodations, contact Learning Enrichment and Disability Services (LEADS) located on second floor Pearsons (north side), 608-363-2572, learning@beloit.edu or make an appointment through joydeleon.youcanbook.me to get an Access Letter. We can then discuss how your learning needs may be appropriately met. You can also apply for free peer tutoring through the Portal (student life tab, then tutoring forms on the left).

Last modified Jan 20, 2022 by Orion Pearce

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